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Ruthenium and iridium complexes are advantageously tunable photoredox catalysts, but the expense of these precious metals is a drawback to their use. Lighter, more abundant metals have been considered unsuitable because of their anticipated rapid relaxation from photoexcited states. Chan et al. report that a cobalt complex with conventional bipyridyl ligands manifests a surprisingly long excited state lifetime, which they attribute to Marcus inverted region behavior (see the Perspective by Yaltseva and Wenger). The Earth-abundant metal is effective at photoredox coupling of aryl amides with aryl boronic acids and more generally opens the door to greater sustainability in this catalyst class.
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