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2024年12月14日,2024年7月8日-15日月亮河畔、龙山

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第14名雪佛龙收跌2.19%成交14.1亿美元谷物商邦吉和雪佛龙周叁表示已经收购了阿根廷农产物公司颁丑补肠谤补蝉别谤惫颈肠颈辞蝉希望扩大其可再生能源业务两家公司表示颁丑补肠谤补蝉别谤惫颈肠颈辞蝉专注于种植高含油量的荠菜将为邦吉和雪佛龙的增加一个新的油源完善全球供应链以满足市场对低碳可再生原料日益增长的需求该交易的财务细节没有披露

咸丰九年(1859年),六公主去世,时年二十八岁。咸丰帝为此特别写了一道上谕:“朕姊寿恩固伦公主、淑慎柔嘉。性敦仁孝。自幼仰承皇考皇妣恩眷。至为优渥。昨闻薨逝。轸惜良深。朕业于昨日前往奠醊。本月十六日。朕再行亲往赐奠。用示眷念优加至意。”那一刻,我们仿佛成为了最亲密的伙伴。

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“suoyichenxianshengdiyishijianjiubarendaidaowozhelilai,shuoqilaiwohuanmeihaohaoganxienijiaxianshengliao。”《kexue》(20221028chuban)yizhoulunwendaodu2022-10-31 14:21·kexuewangbianyi | weijiuScience, 28 OCTOBER 2022, VOL 378, ISSUE 6618《kexue》2022nian10yue28ri,di378juan,6618qitianwenxueAstronomyLargest recent impact craters on Mars: Orbital imaging and surface seismic co-investigationhuoxingshangzuijinzuidadezhuangjikeng:guidaochengxianghebiaomiandizhenlianhediaocha▲ zuozhe:L. V. POSIOLOVA, P. LOGNONN?, W. B. BANERDT, J. CLINTON, G. S. COLLINS, T. KAWAMURA, ET AL.▲ lianjie:https://www.science.org/doi/10.1126/science.abq7704▲ zhaiyao:2021nianxiabannian,huoxingshangxingchengliaolianggezhijing>130midezhuangjikeng。zheshihuoxingzhenchaguidaofeixingqizi16nianqiankaishiyunxingyilaifaxiandelianggezuidadexinzhuangjikeng。gaizhuangjizaochengliaodongchahaozaiqi3nianrenwuqijianjiludeliangcizuidadizhenshijian(zhenjidayu4ji)。guidaotuxianghedizhendimianyundongdejiehe,shirenmennenggouyanjiudaqixibaoxingxingzhuangjiguochengdedixiahedaqinengliangfenpei,bingshoucizhijieceshiyizhishijianjulidehuoxingshenbu-neibudizhenmoxing。35°Ndezhuangjichuwachuliaodakuaideshuibing,zheshizaihuoxingshangzhijieguanchadaobingdezuidiweidu。▲ Abstract:Two >130-meter-diameter impact craters formed on Mars during the later half of 2021. These are the two largest fresh impact craters discovered by the Mars Reconnaissance Orbiter since operations started 16 years ago. The impacts created two of the largest seismic events (magnitudes greater than 4) recorded by InSight during its 3-year mission. The combination of orbital imagery and seismic ground motion enables the investigation of subsurface and atmospheric energy partitioning of the impact process on a planet with a thin atmosphere and the first direct test of martian deep-interior seismic models with known event distances. The impact at 35°N excavated blocks of water ice, which is the lowest latitude at which ice has been directly observed on Mars.Surface waves and crustal structure on Marshuoxingbiaomianbohedikejiegou▲ zuozhe:D. KIM, W. B. BANERDT, S. CEYLAN, D. GIARDINI, V. LEKI?, P. LOGNONN?, ET AL.▲ lianjie:https://www.science.org/doi/10.1126/science.abq7157▲ zhaiyao:yanjiuzutancedaohuoxingshangliangkeyunshizhuangjichanshengdebiaomianbo。tongguoceliangzhuangjizhuoluqilujingshangdequnsudumisan,tamenhuodeliaoyuanlidongchahaozhuoluqidedikejiegoudezhijieyueshutiaojian。chidaoerfenxianyibeidedikezai5~30qianmishendufanweineidehengbosuduyueweimeimiao3.2qianmi,shendubianhuabuda。zheyiweizhuozhuoluqixiafangdedikemidubituicedeyaogao,biaomingbiaomianbochuanguodehuoshanquyuyaomechengfenbutong,yaomekongxidujianshao。zaizhuoludianxiafang10qianmishenchuguanchadaojiaodidesuduhedikefencengbingfeiyigequanqiuxingtezheng。biaomianbojieshidejiegoubianhuaduihuoxingdikexingchenghehoududemoxingjuyouzhongyaoyiyi。▲ Abstract:We detected surface waves from two meteorite impacts on Mars. By measuring group velocity dispersion along the impact-lander path, we obtained a direct constraint on crustal structure away from the InSight lander. The crust north of the equatorial dichotomy had a shear wave velocity of approximately 3.2 kilometers per second in the 5- to 30-kilometer depth range, with little depth variation. This implies a higher crustal density than inferred beneath the lander, suggesting either compositional differences or reduced porosity in the volcanic areas traversed by the surface waves. The lower velocities and the crustal layering observed beneath the landing site down to a 10-kilometer depth are not a global feature. Structural variations revealed by surface waves hold implications for models of the formation and thickness of the martian crust.cailiaokexueMaterials SciencePlastic deformation in silicon nitride ceramics via bond switching at coherent interfacesdanhuaguitaocizaigonggejiemianshangtongguojianqiehuanchanshengsuxingbianxing▲ zuozhe:JIE ZHANG, GUANGHUA LIU, WEI CUI, YIYAO GE, SONGMO DU, YIXUAN GAO, ET AL.▲ lianjie:https://www.science.org/doi/10.1126/science.abq7490▲ zhaiyao:gongjiajianhetaocijuyouyouyidexingneng(baokuoyingdu、qiangdu、huaxueduoxing、nairexinghenaifushixing),danyouyuqishiwencuixing,ruheshixiangengguangfandeyingyongpojutiaozhan。yujinshuzhongdeyuanzikeyiyanzhuohuayimianhuadongyibianxingbutong,gongjiajianhetaociyouyuyuanzijiangongjiajiandeqiangdingxiangxing,qibianxingxuyaoduanjian。zhezuizhonghuidaozhijiazaishifashengduanlie。yanjiuzutichuliaoyizhongkebianxinggongjiajianhedanhuagui(Si3N4)taocideshejifangfa,qitedianshijuyougonggejiemiandeshuangxiangjiegou。zaigonggejiemianshangshixianliaolianxujianqiehuan,zheyouliyuyingliyoudaoxiangbian,bingzuizhongchanshengsuxingbianxingnengli。▲ Abstract:Covalently bonded ceramics exhibit preeminent properties—including hardness, strength, chemical inertness, and resistance against heat and corrosion—yet their wider application is challenging because of their room-temperature brittleness. In contrast to the atoms in metals that can slide along slip planes to accommodate strains, the atoms in covalently bonded ceramics require bond breaking because of the strong and directional characteristics of covalent bonds. This eventually leads to catastrophic failure on loading. We present an approach for designing deformable covalently bonded silicon nitride (Si3N4) ceramics that feature a dual-phase structure with coherent interfaces. Successive bond switching is realized at the coherent interfaces, which facilitates a stress-induced phase transformation and, eventually, generates plastic deformability.huaxueChemistryStereochemical editing logic powered by the epimerization of unactivated tertiary stereocentersweijihuosanjilitizhongxindechaxiangyigouzhulilitihuaxuebianjiluoji▲ zuozhe:YU-AN ZHANG, VIGNESH PALANI, ALEXANDER E. SEIM, YONG WANG, KATHLEEN J. WANG AND ALISON E. WENDLANDT.▲ lianjie:https://www.science.org/doi/10.1126/science.add6852▲ zhaiyao:fuzamubiaowudelitixuanzexinghechengxuyaojingquedehuaxuezhuanhuanxiediao,tongshijianlisuoxujiandeliantongxinghekongjiandingxiang。zaizhexianggongzuozhong,yanjiuzumiaoshuliaoyizhongshouxingfenzijiqiyigoutihechengdehubufanshi,jizaihouqidiaozhengfenzidesanweijiegou。zheyiceluechenggongdeguanjianshikaifaliaoyizhongwenheqiegaodutongyongdeguangcuihuafangfa,tayoushiwusuanyanjuyinliziheerliuhuawuzhucuihuajizucheng,shixianqiangouxinggudingdeweijihuosanjishengchengzhongxinshixianxianghuzhuanhua。yanjiuzutongguokuaisugoujianshiyongxianyougongjuhennanzhibeideshouxingzhijia,yijifuzamubiaowudehouqilitibianji,zhanshiliaozhezhongfangfadeduogongnengxing(yijilitibianjiluojideshixian)。▲ Abstract:The stereoselective synthesis of complex targets requires the precise orchestration of chemical transformations that simultaneously establish the connectivity and spatial orientation of desired bonds. In this work, we describe a complementary paradigm for the synthesis of chiral molecules and their isomers, which tunes the three-dimensional structure of a molecule at a late stage. Key to the success of this strategy is the development of a mild and highly general photocatalytic method composed of decatungstate polyanion and disulfide cocatalysts, which enable the interconversion of unactivated tertiary stereogenic centers that were previously configurationally fixed. We showcase the versatility of this method—and the implementation of stereoediting logic—by the rapid construction of chiral scaffolds that would be challenging to access using existing tools and by the late-stage stereoediting of complex targets.Closed-loop optimization of general reaction conditions for heteroaryl Suzuki-Miyaura couplingzafangjiSuzuki-Miyauraoulianfanyingtongyongtiaojiandebihuanyouhua▲ zuozhe:NICHOLAS H. ANGELLO, VANDANA RATHORE, WIKTOR BEKER, AGNIESZKA WO?OS, EDWARD R. JIRA, RAFA? ROSZAK, ET AL.▲ lianjie:https://www.science.org/doi/10.1126/science.adc8743▲ zhaiyao:youjifanyingdetongyongtiaojianhenzhongyao,danquehanjian,quedingtamendenulitongchangzhikaolvhuaxuekongjiandexiazhaiquyu。yaofaxiangengtongyongdefanyingtiaojian,jiuxuyaokaolvcongdajuzhenjizhihegaoweifanyingtiaojianjizhijiaochaerchengdehuaxuekongjiandeguangkuoquyu,zheshidexiangjindeshiyanbuqieshiji。yanjiuzubaodaoliaoyigejiandandebihuangongzuoliu,liyongshujuyindaojuzhenxiangxiaxuanze、buquedingxingzuixiaohuajiqixuexihejiqirenshiyanlaifaxiantongyongfanyingtiaojian。yingyongyuzafangjiSuzuki-Miyaurajiaochaoulianzhezhongjijutiaozhanxinghezhongyaoxingdewentishi,yanjiuzuquedingliaoyigetongyongtiaojian,yuzhiqianshiyongchuantongfangfakaifadeguangfanshiyongdejizhunxiangbi,pingjunchanlvfanliaoyifan。gaiyanjiuweijiejuejuyoudasousuokongjiandeduoweihuaxueyouhuawentitigongliaoyigeshiyongdeluxiantu。▲ Abstract:General conditions for organic reactions are important but rare, and efforts to identify them usually consider only narrow regions of chemical space. Discovering more general reaction conditions requires considering vast regions of chemical space derived from a large matrix of substrates crossed with a high-dimensional matrix of reaction conditions, rendering exhaustive experimentation impractical. Here, we report a simple closed-loop workflow that leverages data-guided matrix down-selection, uncertainty-minimizing machine learning, and robotic experimentation to discover general reaction conditions. Application to the challenging and consequential problem of heteroaryl Suzuki-Miyaura cross-coupling identified conditions that double the average yield relative to a widely used benchmark that was previously developed using traditional approaches. This study provides a practical road map for solving multidimensional chemical optimization problems with large search spaces.gonggongweishengPublic HealthEvolution and antiviral activity of a human protein of retroviral originnizhuanlubingdulaiyuanrenleidanbaizhidejinhuahekangbingduhuoxing▲ zuozhe:JOHN A. FRANK, MANVENDRA SINGH, HARRISON B. CULLEN, RAPHAEL A. KIROU, MERIEM BENKADDOUR-BOUMZAOUAD, JOSE L. CORTES, ET AL.▲ lianjie:https://www.science.org/doi/10.1126/science.abq7871▲ zhaiyao:neiyuanxingnizhuanlubingdushiyuanzigulaozhongxiganrandeburudongwujiyinzudefengfuzuchengbufen。zaiyixieburudongwuzhong,youzhexieyuanjianbianmadebaomodanbaikeyidiyuwaiyuanxingbingdu,danzhezhonghuoxingzairenleineiyuanxingbiaodadebaomozhongshangweibeizhengshi。yanjiuzubaodao,renleijiyinzuyongyoudaliangbaomoyanshengxulie,juyouyizhinizhuanlubingduganrandeqianli。weiliaoyanzhengzheyidian,tamenduibaomoyanshengdanbaiSuppressynjinxingliaobiaozheng。jieguofaxianSuppressynzairenleizhuochuangqianpeitaihefayuzhongdetaipanzhong,shiyongqizuxiannizhuanlubingduqidongzibiaoda。xibaopeiyangfenxibiaoming,SuppressynjiqileirenzhixitongyuanwukeyizhixiancunburudongwuDxingnizhuanlubingdudeganran。gaishujuzhichisuzhumianyihejiyinzufangyudenizhuanlubingdubaomogongxuanzedetongyongmoxing。▲ Abstract:Endogenous retroviruses are abundant components of mammalian genomes descended from ancient germline infections. In several mammals, the envelope proteins encoded by these elements protect against exogenous viruses, but this activity has not been documented with endogenously expressed envelopes in humans. We report that the human genome harbors a large pool of envelope-derived sequences with the potential to restrict retroviral infection. To test this, we characterized an envelope-derived protein, Suppressyn. We found that Suppressyn is expressed in human preimplantation embryos and developing placenta using its ancestral retroviral promoter. Cell culture assays showed that Suppressyn, and its hominoid orthologs, could restrict infection by extant mammalian type D retroviruses. Our data support a generalizable model of retroviral envelope co-option for host immunity and genome defense.

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