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《kexue》(20220527chuban)yizhoulunwendaodu2022-05-29 21:39·kexuewangbianyi | liyanScience,27 MAY 2022, Volume 376 Issue 6596《kexue》2022nian5yue27ri,di376juan,6596qicailiaokexueMaterials ScienceFerroelectricity in untwisted heterobilayers of transition metal dichalcogenidesguodujinshuerluzuhuahewuweiniuquyishuangcengzhongdetiedianxing▲ zuozhe:LUKAS ROG?E, LVJIN WANG, YI ZHANG, SONGHUA CAI et al.▲ lianjie:https://www.science.org/doi/10.1126/science.abm5734▲ zhaiyao:juyoumianwaitiedianheyadiantexingdeerweicailiaoshishixianchaobaotieheyadiandianziqijiandelixiangcailiao。womentongguoyibuhuaxueqixiangchenjifahechengliaoweiniuqu、xiangchenghewaiyandeMoS2/WS2yizhishuangcengcailiao,yiwaizhengmingliaoOOPtiedianxingheyadianxing。womendedaoded33yadianchangshuwei1.95 ~ 2.09pimi/fu,bidancengIn2Se3deziranOOPyadianchangshuda6bei。tongguogaibianMoS2/WS2yizhishuangcengdejihuazhuangtai,womenzhengmingliaoxiangyingtiediansuidaojieqijianzhongsuichuandianliukejinxingyuesangeshuliangjidiaozhi。womendejieguoyumidufanhanlilunshiyizhide,zhebiaomingduichengxingpoquehecengjianhuadongduchanshengliaoyixiangbudaodexingzhi,erbuxuyaodiaoyongniuqujiaohuomoerchou。▲ Abstract:Two-dimensional materials with out-of-plane (OOP) ferroelectric and piezoelectric properties are highly desirable for the realization of ultrathin ferro- and piezoelectronic devices. We demonstrate unexpected OOP ferroelectricity and piezoelectricity in untwisted, commensurate, and epitaxial MoS2/WS2 heterobilayers synthesized by scalable one-step chemical vapor deposition. We show d33 piezoelectric constants of 1.95 to 2.09 picometers per volt that are larger than the natural OOP piezoelectric constant of monolayer In2Se3 by a factor of ~6. We demonstrate the modulation of tunneling current by about three orders of magnitude in ferroelectric tunnel junction devices by changing the polarization state of MoS2/WS2 heterobilayers. Our results are consistent with density functional theory, which shows that both symmetry breaking and interlayer sliding give rise to the unexpected properties without the need for invoking twist angles or moiré domains.huaxueChemistryHydrotrioxide (ROOOH) formation in the atmospherezaidaqizhongxingchengdeqingsanyanghuawu(ROOOH)▲ zuozhe:TORSTEN BERNDT, JING CHEN, EVA R. KJ?RGAARD et al.▲ lianjie:https://www.science.org/doi/10.1126/science.abn6012▲ zhaiyao:youjiqingsanyanghuawu(ROOOH)shiyongyuyoujihechengdeqiangyanghuaji。ciqian,yanjiutuicetamenshizaidaqizhongtongguoyoujiguoyangziyouji(RO2)yuqingyangziyouji(OH)deqixiangfanyingxingchengde。zaici,womenbaogaoliaocongjigedaqixiangguandeRO2ziyoujizhongzhijieguanchadaoROOOHdexingcheng。donglixuefenxizhengshiRO2 + OHkuaisufanyingxingchengROOOH,sulvxishujiejinpengzhuangjixian。duiyuqingyangziyoujiyinfadeyiwuerxijiangjie,quanqiumoxingyucesanyanghuaerqingmoershengchenglvgaoda1%,zheyiweizhuomeinianyueyou1000wandundeROOOHshengcheng。ROOOHzaidaqizhongdeshoumingyujiweijifenzhongdaojixiaoshi。qingsanyanghuawushidaqizhongxianqianbeihuluedeyileiwuzhi,qiyingxiangxuyaojinyibuyanjiu。▲ Abstract:Organic hydrotrioxides (ROOOH) are known to be strong oxidants used in organic synthesis. Previously, it has been speculated that they are formed in the atmosphere through the gas-phase reaction of organic peroxy radicals (RO2) with hydroxyl radicals (OH). Here, we report direct observation of ROOOH formation from several atmospherically relevant RO2 radicals. Kinetic analysis confirmed rapid RO2 + OH reactions forming ROOOH, with rate coefficients close to the collision limit. For the OH-initiated degradation of isoprene, global modeling predicts molar hydrotrioxide formation yields of up to 1%, which represents an annual ROOOH formation of about 10 million metric tons. The atmospheric lifetime of ROOOH is estimated to be minutes to hours. Hydrotrioxides represent a previously omitted substance class in the atmosphere, the impact of which needs to be examined.Dynamic interplay between metal nanoparticles and oxide support under redox conditionsyanghuahuanyuantiaojianxiajinshunamiliziheyanghuawuzaitizhijiandedongtaixianghuzuoyong▲ zuozhe:H. FREY, A. BECK, X. HUANG et al.▲ lianjie:https://www.science.org/doi/10.1126/science.abm3371▲ zhaiyao:guijinshukelihekehuanyuanjinshuyanghuawuzaitizhijiandedongtaixianghuzuoyongyilaiyuyuzhouweiqitideyanghuahuanyuanfanying。toushedianzixianweijingxianshi,dangxitongbaoluzaihanyangheqingdeyanghuahuanyuanfanyinghuanjingzhong,zaihuanyuantiaojianxiaguanchadaode、baoguozaieryanghuazuoshangdejinshu-zaitiqiangxianghuzuoyong(SMSI)youdaodebokelizai1 bar yalixiaxiaoshiliao。jinshuyanghuawudebuwendingheyanghuahuanyuanjiedaodeeryanghuazuozhonggoudaozhiliaoyilaiyunamiliziquxiangdelizidonglixuehedingxiangqianyi。dangzhuanhuichunyanghuatiaojianshi,SMSIjingtaizhuangtaibeizhongxinjianli。zhexiangyanjiuqiangdiaoliaofanyingtaihefeifanyingtaizhijiandechayi,bingbiaomingjinshu-zaitixianghuzuoyongdebiaoxianqiangliediyilaiyuhuaxuehuanjing。▲ Abstract:The dynamic interactions between noble metal particles and reducible metal-oxide supports can depend on redox reactions with ambient gases. Transmission electron microscopy revealed that the strong metal-support interaction (SMSI)–induced encapsulation of platinum particles on titania observed under reducing conditions is lost once the system is exposed to a redox-reactive environment containing oxygen and hydrogen at a total pressure of ~1 bar. Destabilization of the metal–oxide interface and redox-mediated reconstructions of titania lead to particle dynamics and directed particle migration that depend on nanoparticle orientation. A static encapsulated SMSI state was reestablished when switching back to purely oxidizing conditions. This work highlights the difference between reactive and nonreactive states and demonstrates that manifestations of the metal-support interaction strongly depend on the chemical environment.diqiukexueEarth SciencePersistent influence of precession on northern ice sheet variability since the early Pleistocenezaogengxinshiyilaisuichaduibeibubinggaibianhuadechixuyingxiang▲ zuozhe:STEPHEN BARKER, AIDAN STARR, JEROEN VAN DER LUBBE et al.▲ lianjie:https://www.science.org/doi/10.1126/science.abm4033▲ zhaiyao:100wannianqian,quanqiubingliangdebianhuazhuyaoshiqingjiaodebianhua;raner,suichachanshenghezhongzuoyongdewentirengranmeiyoujiejue。tongguoguoqu170wanniandebeidaxiyangbingpiaoliujilu,womenfaxiantedingbingchuanzhouqi(fanyingliaobinggaidekuozhang)zhongbingpiaoliuqishitongchangchixuzaiqingjiaojiaoshaoerdaguimobingxiaorongshijianduyusuichadezuixiaozhixiangguan。ciwai,womendeyanjiujieguobiaoming,zaizhong-wangengxinshishiqi,yousuichaqudongdedaguimoxiaorongshijianyubingxiaoqizhijianpubiancunzaiguanlian。zaizengjiafashengqian,qingjiaobenshenjiuzuyijieshuyicibingqixunhuan,zaiyue100wannianyihou,suizhuobeibanqiubingyuandenanyan,qingjiaoshiquliaoduibingchuanxiaotuidezhudaozuoyong。▲ Abstract:Prior to ~1 million years ago (Ma), variations in global ice volume were dominated by changes in obliquity; however, the role of precession remains unresolved. Using a record of North Atlantic ice rafting spanning the past 1.7 million years, we find that the onset of ice rafting within a given glacial cycle (reflecting ice sheet expansion) consistently occurred during times of decreasing obliquity whereas mass ice wasting (ablation) events were consistently tied to minima in precession. Furthermore, our results suggest that the ubiquitous association between precession-driven mass wasting events and glacial termination is a distinct feature of the mid to late Pleistocene. Before then (increasing), obliquity alone was sufficient to end a glacial cycle, before losing its dominant grip on deglaciation with the southward extension of Northern Hemisphere ice sheets since ~1 Ma.Where rivers jump courseheliu“tiaoyue”dedifang▲ zuozhe:SAM BROOKE, AUSTIN J. CHADWICK, JOSE SILVESTRE et al.▲ lianjie:https://www.science.org/doi/10.1126/science.abm1215▲ zhaiyao:zaihanjiandeheliuchonglieshijianzhong,heliuhuiturangaidao,daozhizainanxingdehongshui。youyushujuxishao,duichonglieweizhidekongzhizhizhishenshao。womenfenxiliaojin50nianlaideweixingtuxiang,bingjiluliaoquanqiu113qichonglieshijian,faxianliaosanzhongbutongdechonglieweizhikongzhi。shantidechongliezuoyongyuguxianbianhuaxiangwenhe,ersanjiaozhoudechongliezuoyongzhuyaojizhongzaihuishuidainei,biaominghongshuiqijianshoukongjianliudejiansuhuojiasukongzhi。raner,sanjiaozhoushang38%dechongliefashengzaihuishuixiaoyingdeshangyou。zhexieshijianfashengzairedaiheshamohuanjinglidouqiao、fuhanchenjiwudeheliuzhong。womendeyanjiujieguobiaoming,sanjiaozhoushangdechonglieweizhishiyoushangyoudehongshuiqinshichengdujuedingde,zhezhongqinshitongchangjuxianyuhuishuiqu,danzaidouqiaodehanshaheliuzhongkeyixiangshangyouyanshen。womendeyanjiufaxianchanmingliaochongliezaihaikenengruhexiangyingtudishiyongheqihoubianhua。▲ Abstract:Rivers can abruptly shift pathways in rare events called avulsions, which cause devastating floods. The controls on avulsion locations are poorly understood as a result of sparse data on such features. We analyzed nearly 50 years of satellite imagery and documented 113 avulsions across the globe that indicate three distinct controls on avulsion location. Avulsions on fans coincide with valley-confinement change, whereas avulsions on deltas are primarily clustered within the backwater zone, indicating a control by spatial flow deceleration or acceleration during floods. However, 38% of avulsions on deltas occurred upstream of backwater effects. These events occurred in steep, sediment-rich rivers in tropical and desert environments. Our results indicate that avulsion location on deltas is set by the upstream extent of flood-driven erosion, which is typically limited to the backwater zone but can extend far upstream in steep, sediment-laden rivers. Our findings elucidate how avulsion hazards might respond to land use and climate change.Models predict planned phosphorus load reduction will make Lake Erie more toxicmoxingyucejihuazhongdelinfuhejianshaojiangshiyilihudeduxinggengda▲ zuozhe:FERDI L. HELLWEGER, ROBBIE M. MARTIN, FALK EIGEMANN et al.▲ lianjie:https://www.science.org/doi/10.1126/science.abm6791▲ zhaiyao:youhaidelanzaojunshiyigequanqiuxingdehuanjingwenti,danwomenquefaduiyouduyufeiyoududejunzhushengtaihedusushengchandekecaozuodeliaojie。womenjinxingliaoyixiangbaohan103pianlunwendedaguimozuozuofenxi,bingliyongtakaifaliaoyigeweinangzaoshengchangheweinangzaodusuchanshengdejixiexingdailirenjimoxing。duiyilihudemonibiaoming,zai2014niantuolaiduoyinyongshuiweijiqijian,guanchadaodechandusudaofeichandusudejunzhuyantishiyoubutongdexibaoyanghuayingjihuanjiecelue(weinangzaodusubaohuvsmeijiangjie)hezhexiejizhiduidandebutongyigandusuokongzhide。zhegemoxingyijiyigegengjiandandejingyanmoxing,duyucejihuazhongdelinfuhejianshaojiangjiangdishengwuliang,danshidanheguanggengrongyihuode,zhejiangzengjiadusudechansheng,youliyuchanduxibao,bingzengjiadusunongdu。▲ Abstract:Harmful cyanobacteria are a global environmental problem, yet we lack actionable understanding of toxigenic versus nontoxigenic strain ecology and toxin production. We performed a large-scale meta-analysis including 103 papers and used it to develop a mechanistic, agent-based model of Microcystis growth and microcystin production. Simulations for Lake Erie suggest that the observed toxigenic-to-nontoxigenic strain succession during the 2014 Toledo drinking water crisis was controlled by different cellular oxidative stress mitigation strategies (protection by microcystin versus degradation by enzymes) and the different susceptibility of those mechanisms to nitrogen limitation. This model, as well as a simpler empirical one, predicts that the planned phosphorus load reduction will lower biomass but make nitrogen and light more available, which will increase toxin production, favor toxigenic cells, and increase toxin concentrations.nveryaoqushangmingpaidaxue,danshibeimuqinjujueliao,muqinpahuaqian,jiubizhuonverqumianfeideshifan。sudaqiangzaiyipangkanzhuo,queyijugongdaohuayebuganshuo。

这(窜丑别)种(窜丑辞苍驳)“遗(驰颈)憾(贬补苍)”还(贬耻补苍)在(窜补颈)扩(碍耻辞)大(顿补),在(窜补颈)院(驰耻补苍)方(贵补苍驳)继(闯颈)续(齿耻)的(顿别)调(顿颈补辞)查(颁丑补)过(骋耻辞)程(颁丑别苍驳)中(窜丑辞苍驳),发(贵补)现(齿颈补苍)涉(厂丑别)案(础苍)人(搁别苍)数(厂丑耻)越(驰耻别)来(尝补颈)越(驰耻别)多(顿耻辞),推(罢耻颈)算(厂耻补苍)最(窜耻颈)终(窜丑辞苍驳)可(碍别)能(狈别苍驳)查(颁丑补)出(颁丑耻)高(骋补辞)达(顿补)80至(窜丑颈)100人(搁别苍)以(驰颈)同(罢辞苍驳)样(驰补苍驳)手(厂丑辞耻)法(贵补)骗(笔颈补苍)取(蚕耻)入(搁耻)学(齿耻别)资(窜颈)格(骋别)。

zuizhong,zaiyifantaojiahuanjiahou,lasikedeyongzhongjinjiangyishabeilamailiaoxialai,zuoweizijidesirenshinv。jinguanyishabeilapinmingfankang,quehuanshibeitadeshouxiaandao,yongmashengshuanliaoqilai。jiuzheyang,tazaicilunweiliaonuli,chengweiliaolasikededesirencaichan。2024-07-05 16:05·shoujizhongguo

据(闯耻)红(贬辞苍驳)星(齿颈苍驳)新(齿颈苍)闻(奥别苍)报(叠补辞)道(顿补辞),1970年(狈颈补苍)出(颁丑耻)生(厂丑别苍驳)的(顿别)张(窜丑补苍驳)蔚(奥别颈)顶(顿颈苍驳)着(窜丑耻辞)“哈(贬补)佛(贵辞)学(齿耻别)霸(叠补)”的(顿别)光(骋耻补苍驳)环(贬耻补苍),职(窜丑颈)业(驰别)生(厂丑别苍驳)涯(驰补)效(齿颈补辞)力(尝颈)过(骋耻辞)通(罢辞苍驳)用(驰辞苍驳)电(顿颈补苍)气(蚕颈)、贝(叠别颈)恩(贰苍)资(窜颈)本(叠别苍)、阿(础)里(尝颈)巴(叠补)巴(叠补)、拉(尝补)尔(贰谤)夫(贵耻)·劳(尝补辞)伦(尝耻苍)等(顿别苍驳)知(窜丑颈)名(惭颈苍驳)企(蚕颈)业(驰别),履(尝惫)历(尝颈)十(厂丑颈)分(贵别苍)光(骋耻补苍驳)鲜(齿颈补苍)。

达米安李重返太阳、英格尔斯1年330万重返森林狼、自由球员多齐尔重返NBA与森林狼签下一份1年合同。这三名球员基本上都是一些边角料,他们的去留无法影响到球队的真实实力。第二天因部分队员体力不支,选择从金顶索道下山。其余人员早7点,继续出发,天气阴,云海很壮观,碧绿的山峰相连,杜鹃花点缀,连绵起伏,犹如仙境,景色确实漂亮,令人心醉。乱伦大杂烩 攵女乱H系列合集多女最新章节-乱伦大杂烩...

回忆中的她总是那样光彩照人在电视屏幕上生动地演绎着各种角色的喜怒哀乐在现实生活中她的感情经历也同样令人动容那些对于刘诗诗和吴奇隆的故事早已深深烙印在粉丝们的心里——从媒体报道的点点滴滴到他们在社交平台上无意间流露出的甜蜜互动一切都显得那么自然而然

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